We propose protocols that probe manifestations of the mass-energy equivalence in an optical lattice clock (OLC) interrogated with spin coherent and entangled quantum states. To tune and uniquely distinguish the mass-energy equivalence effects (gravitational redshift and second order Doppler shift) in such setting, we devise a dressing protocol using an additional nuclear spin state. We then analyze the interplay between photon-mediated interactions and gravitational redshift and show that such interplay can lead to entanglement generation and frequency synchronization. In the regime where all atomic spins synchronize, we show the synchronization time depends on the initial entanglement of the state and can be used as a proxy of its metrological gain compared to a classical state. Our work opens new possibilities for exploring the effects of general relativity on quantum coherence and entanglement in OLC experiments.

We present a biased atomic qubit, universally implementable across all atomic platforms, encoded as a `spin-cat' within ground state Zeeman levels. The key characteristic of our configuration is the coupling of the ground state spin manifold of size Fg≫1 to an excited Zeeman spin manifold of size Fe=Fg−1 using light. This coupling results in eigenstates of the driven atom that include exactly two dark states in the ground state manifold, which are decoupled from light and immune to spontaneous emission from the excited states. These dark states constitute the `spin-cat', leading to the designation `dark spin-cat'. We demonstrate that under strong Rabi drive and for large Fg, the `dark spin-cat' is autonomously stabilized against common noise sources and encodes a qubit with significantly biased noise. Specifically, the bit-flip error rate decreases exponentially with Fg relative to the dephasing rate. We provide an analysis of dark spin-cats, their robustness to noise, and discuss bias-preserving single qubit and entangling gates, exemplified on a Rydberg tweezer platform.

Topologically ordered quantum matter exhibits intriguing long-range patterns of entanglement, which reveal themselves in subsystem entropies. However, measuring such entropies, which can be used to certify topological order, on large partitions is challenging and becomes practically unfeasible for large systems. We propose a protocol based on local adiabatic deformations of the Hamiltonian which extracts the universal features of long-range topological entanglement from measurements on small subsystems of finite size, trading an exponential number of measurements against a polynomial-time evolution. Our protocol is general and readily applicable to various quantum simulation architectures. We apply our method to various string-net models representing both abelian and non-abelian topologically ordered phases, and illustrate its application to neutral atom tweezer arrays with numerical simulations.